Chemistry and creativity: Metal Nanoparticles: Synthesis, Characterization, and Applications
Metal Nanoparticles: Synthesis, Characterization, and Applications
Metal nanoparticles are certain to be the building blocks of the next generation of
electronic, optoelectronic and chemical sensing devices. The physical limits imposed
by top-down methods such as photo- and electron- beam lithography dictate
that the synthesis and assembly of functional nanoscale materials will become
the province of chemists. In the current literature, there are three emerging
themes in nanoparticle research: synthesis and assembly of metal particles of
well-defined size and geometry, structural and surface chemistry effects on
single electron charging, and size, shape, and surface chemistry effects on particle
optical properties.
Over the last decade there has been increased interest in “nanochemistry.” A variety
of supermolecular ensembles , multifunctional supermolecules , carbon
nanotubes , and metal and semiconductor nanoparticles have been synthesized
and proposed as potential building blocks of optical and electronic devices
. This has arisen for a variety of reasons, not the least of which is technological
advance, and the promise of control over material and device structure at length
scales far below conventional lithographic patterning technology
Author:
Daniel L. Feldheim
North Carolina State University, Raleigh, North Carolina
Colby A. Foss, Jr.
Georgetown University, Washington, D.C.
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1.Overview 1
Daniel L. Feldheim, and Colby A. Foss, Jr.
2.Transition-Metal Nanoclusters: Solution-Phase Synthesis, 17
Then Characterization and Mechanism of Formation, ofPolyoxoanion- and Tetrabutylammonium-Stabilized Nanoclusters
Richard G. Finke
3.Magic Numbers in Clusters: Nucleation and Growth Sequences
Bonding, Principles, and Packing PatternsBoon K. Teo and Hong Zhang
4.Modeling Metal Nanoparticle Optical Properties
K. Lance Kelly, Traci R. Jensen, Anne A. Lazarides, and George C.Schatz
5.Electrochemical Template Synthesis of Nanoscopic Metal Particles
Colby A. Foss, Jr.6.Nonlinear Optical Properties of Metal Nanoparticles
Robert C. Johnson and Joseph T. Hupp7.Electrochemical Synthesis and Optical Properties of Gold Nanorods 163
Chao-Wen Shih, Wei-Cheng Lai, Chuin-Chieh Hwang,Ser-Sing Chang, and C. R. Chris Wang
8.Surface Plasmon Resonance Biosensing with Colloidal
Au AmplificationMichael J. Natan and L. Andrew Lyon
9.Self-Assemblies of Nanocrystals: Fabrication and Collective
PropertiesMarie-Paule Pileni
10.Electrodeposition of Metal Nanoparticles on Graphite and Silicon 237
Sasha Gorer, Hongtao Liu, Rebecca M. Stiger, Michael P. Zach,James V. Zoval, and Reginald M. Penner
11.Synthesis, Characterization, and Applications
Dendrimer-Encapsulated Metal and Semiconductor NanoparticlesRichard M. Crooks, Victor Chechik, Buford I. Lemon III, Li Sun,
Lee K. Yeung, and Mingqi Zhao
12.The Electrochemistry of Monolayer Protected Au Clusters
David E. Cliffel, Jocelyn F. Hicks, Allen C. Templeton, andRoyce W. Murray
13.Nanoparticle Electronic Devices: Challenges and Opportunities
Wyatt McConnell, Louis C. Brousseau III, A. Blaine House,Lisa B. Lowe, Robert C. Tenent, and Daniel L. Feldheim
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